Here is the full list of all 33 Half-Life 2 achievements. It takes around 12-15 hours to unlock all of the achievements on Windows.
Discover the hidden singing vortigaunt cave in chapter Water Hazard.
Find all lambda caches in Half-Life 2.
Survive the rooftop strider battle in the ruins of City 17.
Break the mini-teleporter in Kleiner's lab.
Kill five enemies with a Manhack.
Play through Ravenholm using only the Gravity Gun.
Kill 3 enemies using the crane.
Cross the antlion beach in chapter Sandtraps without touching the sand.
Use DOG's ball to make a basket in Eli's scrapyard.
Find the HEV Suit Charger faceplate in Eli's scrapyard.
Kill five barnacles with one barrel.
Disintegrate 15 soldiers by throwing them into a Combine ball field.
Shut down the supression device by disabling its generators.
Kill all of the snipers in City 17.
Survive the generator plaza standoff in chapter Anticitizen One.
Get through the toxic tunnel under City 17 in Half-Life 2.
Gain command of a squad of rebels in the uprising.
Survive the second turret standoff in Nova Prospekt.
Kill an enemy with a toilet.
Use the antlions to kill 50 enemies.
Destroy six gunships in Half-Life 2.
Pin a soldier to the billboard in chapter Highway 17.
Get the Gravity Gun in Black Mesa East.
Destroy the hunter-chopper in Half-Life 2.
Get the airboat's mounted gun.
Get the airboat.
Get the crowbar.
Escape the apartment block raid.