Here is the full list of all 50 South Park: The Stick of Truth achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
You knocked out 3 or more enemies with a single fart outside of battle.
You interrupted 5 channel attacks by using a fart.
Gingers have bitten you 3 times without you blocking.
Everyone in South Park is your friend.
You own all the weapons and costumes available in the game.
You've collected all of the available costumes.
You collected all of the Chinpokomon.
You completed the game and never ended a battle with your buddy knocked out.
You completed the game without selling any items.
You watched your parents have sex for 60 seconds.
You defeated the High Jew Elf Kyle in battle.
You defeated the Meth Tweekers while wearing the Evil Cartman goatee and bald cap.
You've let Kenny die in combat 10 times over the course of the game.
You defeated Princess Kenny while living with Dire AIDS.
You've farted on a dog while in gnome form.
You've farted on animals 25 times.
You've farted on people 100 times.
In three separate battles, you've taken a shit in your pants.
You've farted on every buddy in the game.
You flung a turd of your own creation at an enemy.
You shat your pants during a boss battle.
You farted on four major authority figures.
You defeated the Boss Hall Monitor while wearing freckles.
You defeated Princess Kenny and recovered the Stick of Truth.
You defeated Princess Kenny while looking like David Hasselhoff.
You defeated Princess Kenny in your girl makeover disguise.
While inside Mr. Slave, you summoned Mr. Slave.
You have collected half of the available costume sets.
You farted on 10 enemies in the world that were knocked out.
You defeated 20 enemies using Cartman's Ass.
You befriended both crab people and gnomes.
You defeated 3 enemies in one battle while your buddy was knocked out.
You opened all of the garages in South Park.
You made friends with half of South Park.
You befriended your father.
You've spent $500.
You sold 300 junk items.
You farted on the corpse of an aborted Nazi Zombie fetus.
You collected 15 Chinpokomon.
You found Jesus while playing as a Jew.
You defeated the Grand Wizard Cartman in battle.
You befriended the Goths, like everyone else playing this game.
You've unlocked all of the upgrades for a New Kid ability.
Over the course of the game, you've scored 100 perfect attacks.
You collected 5 Chinpokomon.
You successfully blocked every enemy attack in a single (non-tutorial) battle.
You completed your first day in South Park.
Over the course of the game, you've blocked 100 attacks.
You have joined the KKK.
You accepted your fate and chose the name Douchebag yourself.