Here is the full list of all 50 South Park: The Stick of Truth achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
While inside Mr. Slave, you summoned Mr. Slave.
You farted on four major authority figures.
You interrupted 5 channel attacks by using a fart.
Everyone in South Park is your friend.
You own all the weapons and costumes available in the game.
You've collected all of the available costumes.
You've spent $500.
You sold 300 junk items.
You collected all of the Chinpokomon.
You defeated Princess Kenny and recovered the Stick of Truth.
You completed the game and never ended a battle with your buddy knocked out.
You completed the game without selling any items.
You defeated Princess Kenny while living with Dire AIDS.
You defeated Princess Kenny while looking like David Hasselhoff.
You defeated Princess Kenny in your girl makeover disguise.
You have collected half of the available costume sets.
You befriended both crab people and gnomes.
You defeated 20 enemies using Cartman's Ass.
You farted on the corpse of an aborted Nazi Zombie fetus.
You've farted on a dog while in gnome form.
You've farted on every buddy in the game.
You befriended your father.
You watched your parents have sex for 60 seconds.
You defeated the Grand Wizard Cartman in battle.
You defeated the High Jew Elf Kyle in battle.
Gingers have bitten you 3 times without you blocking.
You befriended the Goths, like everyone else playing this game.
You made friends with half of South Park.
You've let Kenny die in combat 10 times over the course of the game.
You opened all of the garages in South Park.
In three separate battles, you've taken a shit in your pants.
You collected 15 Chinpokomon.
You defeated 3 enemies in one battle while your buddy was knocked out.
You completed your first day in South Park.
Over the course of the game, you've scored 100 perfect attacks.
You have joined the KKK.
You shat your pants during a boss battle.
You knocked out 3 or more enemies with a single fart outside of battle.
You've unlocked all of the upgrades for a New Kid ability.
You defeated the Boss Hall Monitor while wearing freckles.
You defeated the Meth Tweekers while wearing the Evil Cartman goatee and bald cap.
You found Jesus while playing as a Jew.
You accepted your fate and chose the name Douchebag yourself.
Over the course of the game, you've blocked 100 attacks.
You've farted on animals 25 times.
You've farted on people 100 times.
You farted on 10 enemies in the world that were knocked out.
You successfully blocked every enemy attack in a single (non-tutorial) battle.
You flung a turd of your own creation at an enemy.
You collected 5 Chinpokomon.