Here is the full list of all 48 LEGO The Lord of the Rings achievements. It takes around 30-35 hours to unlock all of the achievements on Windows.
Get 100%. (Single Player Only)
Unlock all characters. (Single Player Only)
Craft every Mithril item. (Single Player Only)
Collect all the Mithril Bricks. (Single Player Only)
Complete all the Fetch Quests in Middle-earth. (Single Player Only)
Collect all the Red Bricks. (Single Player Only)
Fish perfectly 20 times by pressing the icon as it flashes.
Travel to Isengard as every playable Hobbit.
Collect more than 10,000,000,000 studs. (Single Player Only)
Achieve True Adventurer in every level. (Single Player Only)
Craft the Fire and Ice Bows. (Single Player Only)
Travel to Trollshaws as Bilbo.
Turn an enemy into a skeleton and make them dance.
Reach the top of Amon Hen without being caught once by Boromir. (Single Player Only)
Complete 'The Mines of Moria' in under 15 minutes.
Dress a character completely in treasure items.
Unlock all the Map Stones in Middle-earth. (Single Player Only)
Complete the Bonus Level.
Use the Ent Draught on Pippin.
Equip Aragorn with the Mushroom Crown.
Defeat 42 Uruk-hai as Legolas.
Complete 2 cooking puzzles.
Throw Gimli 30 times.
Defeat Gollum as Gollum.
Complete 'Mount Doom'.
Complete 'The Black Gate'.
Complete 'The Battle of Pelennor Fields'.
Defeat an Oliphaunt as Legolas.
Complete 'The Paths of the Dead'.
Walk into Mordor.
Complete 'Cirith Ungol'.
Complete 'The Secret Stairs'.
Complete 'Osgiliath'.
Complete 'Helm's Deep'.
Finish one of Gimli's opponents as Legolas in 'Helm's Deep'.
Complete 'Warg Attack'.
Complete 'Track Hobbits'.
Complete 'The Dead Marshes'.
Complete 'Taming Gollum'.
Complete 'Amon Hen'.
Complete 'The Mines of Moria'.
Complete 'The Pass of Caradhras'.
Form The Fellowship of the Ring.
Complete 'Weathertop'.
During 'Prologue', jump into the fires of Mount Doom as Isildur.
Complete a level in co-op.
Complete 'The Black Rider'.
Complete 'Prologue'.