Here is the full list of all 48 LEGO The Lord of the Rings achievements. It takes around 30-35 hours to unlock all of the achievements on Windows.
Get 100%. (Single Player Only)
Unlock all characters. (Single Player Only)
Craft every Mithril item. (Single Player Only)
Collect all the Mithril Bricks. (Single Player Only)
Complete all the Fetch Quests in Middle-earth. (Single Player Only)
Collect more than 10,000,000,000 studs. (Single Player Only)
Collect all the Red Bricks. (Single Player Only)
Travel to Trollshaws as Bilbo.
Turn an enemy into a skeleton and make them dance.
Travel to Isengard as every playable Hobbit.
Use the Ent Draught on Pippin.
Dress a character completely in treasure items.
Complete 'The Mines of Moria' in under 15 minutes.
Defeat Gollum as Gollum.
During 'Prologue', jump into the fires of Mount Doom as Isildur.
Unlock all the Map Stones in Middle-earth. (Single Player Only)
Fish perfectly 20 times by pressing the icon as it flashes.
Achieve True Adventurer in every level. (Single Player Only)
Equip Aragorn with the Mushroom Crown.
Defeat an Oliphaunt as Legolas.
Throw Gimli 30 times.
Craft the Fire and Ice Bows. (Single Player Only)
Complete a level in co-op.
Walk into Mordor.
Complete the Bonus Level.
Complete 2 cooking puzzles.
Complete 'Mount Doom'.
Complete 'The Black Gate'.
Complete 'The Battle of Pelennor Fields'.
Complete 'The Paths of the Dead'.
Complete 'Cirith Ungol'.
Complete 'The Secret Stairs'.
Complete 'Osgiliath'.
Complete 'Helm's Deep'.
Defeat 42 Uruk-hai as Legolas.
Finish one of Gimli's opponents as Legolas in 'Helm's Deep'.
Complete 'The Dead Marshes'.
Complete 'Warg Attack'.
Complete 'Track Hobbits'.
Complete 'Taming Gollum'.
Complete 'Amon Hen'.
Reach the top of Amon Hen without being caught once by Boromir. (Single Player Only)
Complete 'The Mines of Moria'.
Complete 'The Pass of Caradhras'.
Form The Fellowship of the Ring.
Complete 'Weathertop'.
Complete 'The Black Rider'.
Complete 'Prologue'.