Here is the full list of all 50 Black Mesa achievements. It takes around 20-25 hours to unlock all of the achievements on Windows.
Escape the Hangar in Surface Tension without alerting the Soldiers.
Kill 10 enemies with Snarks.
Kill 20 enemies with the Hivehand.
Overcharge it anyway.
Conduct all of the questionable research experiments.
Get killed by your own Snarks.
Headshot 20 enemies with the .357 magnum.
Kill an Assassin with the .357 Magnum.
Kill 10 Enemies with Tripmines.
Kill a Barnacle with a Satchel.
Help the Barnacle and Headcrab find true love.
Kill a Marine with their own grenade.
Kill 10 enemies with a reprogrammed Sentry.
Kill 10 Airborne Headcrabs using the Shotgun.
Assemble all the possible Scientists and Guards at the end of Office Complex.
Use the alternate path in Office Complex.
Kill 5 enemies with one grenade.
Cook a Grenade for too long.
Kill a Headcrab using fire.
Perform surgical caffeine extraction from 20 machines.
Refuse to insert the specimen into the Anti-Mass Spectrometer.
Die in the AMS Beam before starting the experiment.
Pass the toilet paper to the scientist in need.
Ruin the microwave casserole.
Interfere with the alarm and laptop in Anomalous Materials.
Drown in Lambda Core's coolant.
Kill an Icthyosaur with either the Tau or Gluon.
Use an entire clip of Gluon ammo in one continuous shot.
Get overtaken by a Headcrab's ample anterior.
Send the Hidden Hat to Xen.
Kill all Protozoans in the Borderworld.
Don't kill any Vortigaunts in the Borderworld.
Carry the Hidden Hat to Endgame.
Wait too long to jump into the Lambda Teleporter.
Skip the opening Xen island with a secret jump.
Use the welcome mat.
Deliver the finishing blow to Gonarch with your Crowbar.
Get whacked into oblivion in the ledge fight.
Find each member of the missing research teams.
Use Cyanogen to kill Gonarch.
Don't use the Cyanogen and let the Gonarch live.
Find the snack supply canister.
Complete Interloper without taking any laser damage.
Escape the Gargantua’s Lair without taking any damage from Gargantuas.
Kill a Controller without killing any of its mind-controlled Vortigaunt slaves.
Take out all three Healing Crystals in Nihilanth’s Chamber at the same time.
Defeat Nihilanth in under 4 minutes.
Accept G-Man’s offer of employment.
Decline G-Man’s offer of employment.
View the *other* secret ending.