Here is the full list of all 54 Baldur's Gate 3 achievements. It takes around 200 hours to unlock all of the achievements on Windows.
Romance the Emperor.
Break Wyll's Pact with Mizora.
Kill a character with an unarmed strike.
Defeat the Apostle of Myrkul before it consumes any Necromites.
Recruit a hireling. You can befriend them or use them as cannon-fodder - we won't judge.
Gift Shadowheart a night orchid - her favourite flower. Always knew she was a softie.
Defeat the Toll Collector without her using gold against you - excellent budgeting.
Kill the Spider Matriarch before her eggs hatch - why do they have so many legs?
Pet Scratch and the Owlbear cub at the same time - the greatest joy an adventurer could ask for.
Ally with Voss against the Githyanki God-Queen. Good luck.
Steal the Blood of Lathander from underneath Rosymorn Monastery.
Break out of prison after being arrested - aren't you daring?
Defeat Commander Zhalk in the Nautiloid.
Leave Act Two - Baldur's Gate is just over the horizon.
Play fetch with Scratch - the best boy in the Realms.
Rescue Sazza from the Emerald Grove, Goblin Camp, and Moonrise Towers in one playthrough.
Rescue all the prisoners from the depths of Moonrise Towers in one playthrough.
Read 100 different books in a single playthrough. Adventuring isn't just daring quests, you know.
Stablise Gale's Netherse orb.
Leave Act One - for somewhere altogether darker.
Complete ten background goals in a single playthrough - you are one with your character.
Long Rest using only alcohol - a time-honoured dwarfish tradition.
Dig up five buried chests in a single playthrough - treasure!
Kill a creature with falling damage.
Take four full long rests in a single playthrough - adventuring's tiring work.
Craft an item in the Adamantine Forge.
Consume a parasite and unlocked a new power - is it meant to wriggle the whole way down?
Let Astarion bite you - ouch.
Successfully use Detect Thoughts to pry into someone's thoughts.
Take control of the Nautiloid and escape the hells.
Perform five attacks in one turn. Your enemies won't know what hit them (literally).
Finish the game (with a heartfelt 'thank you!'' from Larian Studios).
Reign with terror: take control of the Netherbrain and bend the world to your will.
Save the day: kill the Netherbrain and destroy the Absolute tadpoles.
Claim your Throne of Blood: take control of the Netherbrain for Bhaal and break the world.
Make the ultimate sacrifice: become a mindflayer to defeat the Netherbrain.
Multiclass into every class in one playthrough without asking Withers to change your character.
Create three unique alchemical solutions in a single playthrough - bottoms up!
Find and summon the quasit Shovel. Or is her name... Fork? Maybe Basket?
Save every tiefling refugee you can throughout the game in a single playthrough.
Coat the streets of Baldur's Gate in blood - become an Unholy Assassin of Bhaal.
Use one enemy as an improvised weapon against another.
Earn a hundred gold from playing sweet, sweet music in a single playthrough.
Kill the Adamantine Golem without using the Forge Hammer.
Kill the Surgeon before he performs surgery on you in combat.
Defeat Gortash in Wyrm's Rock without activating any traps.
Kill Orin while her cultists are performing their ritual chant.
Kill the Red Dragon in the Upper City.
In the Wyrmway, wait until the dragon is midflight, then knock it out of the sky - KAPOW.
Defeat twenty opponents while a party character is drunk in a single playthough - down them.
Go on a date with Karlach - now that's playing with fire.
Become Bhaal's ultimate weapon - become his Slayer.
Complete the game in Tactician mode.
Complete the game in Honour mode.