Here is the full list of all 31 Twilight Struggle achievements.
Play the China Card.
Headline a scoring card.
Win a game without playing the China Card.
Win a game without ever sending a card to the space race.
Win a game after opponent reaches 18 on the Victory Point Track.
Gain 3 VP from Arms Race when it is drawn for Missile Envy.
As USSR, gain 3 VP from We Will Bury You while U-2 Incident is in play.
As USSR, gain 6 VP from OPEC.
As US, gain 7 VP from Alliance for Progress.
As US, play "The Voice of America" three times in one game.
As US, play "The Voice of America" during Turn 10, AR8 US.