Here is the full list of all 28 The Hex achievements. It takes around 8-10 hours to unlock all of the achievements on Windows.
Crashed Walk
Receive 4 card readings from Catarina in Walk.
Wooed a Great Kraken.
Perform a 360 No Scope with the sniper rifle.
Crashed Waste World.
Crashed Secrets of Legendaria.
Find Missing No. in Secrets of Legendaria.
Deal at least 500 damage in a single strike in Secrets of Legendaria.
Free Vallamir.
Buy 10 upgrades from the Scrap Shop in Waste World.
Crack all the vending machines at The Six Pint.
Crashed Combat Arena X.
Learn all of Catarina's secrets in Super Weasel Kid.
Complete the original Super Weasel Kid without any help from Mr. Shrewd.
Score a true KO on Alley Gator in Combat Arena X.
Crashed Super Weasel Kid '09.
Opened The Hex.
Completed ???'s memory.
Help Rebecha survive the first wave in Walk.
Completed Lazarus' memory.
Completed Rust's memory.
Discovered the truth about Mr. Shrewd.
Activate a gated mod in Waste World.
Completed Chandrelle's memory.
Completed Bryce's memory.
Score a 1000 hit combo in Combat Arena X.
Crack a soda vending machine at The Six Pint.
Completed Super Weasel Kid's memory.