Here is the full list of all 40 Pickers achievements.
Buy an Accordion
Buy a group of items at less than 65% of the asking price
Complete each hidden object game without using the scanner
Find all 60 keys
Explore every scene, hidden object game, and close up in the first 6 location
Combine a Suit of Armor with a Sword
Buy CJ Baxter's safe
Buy a WWII Helmet
Buy a Snow Globe
Collect 40 keys to unlock Unlimited Hidden Object Mode
Buy a Jukebox
Buy a Sun Clock
Bring an owner's mood from angry (red) to happy (green) in one day
Buy a Movie Projector
Restore all items before they are sold
Complete each hidden object game without using any hints
Make a 300% profit in an auction
Create 10 new items using the combine tool
Unlock all locations in the game
Buy an item at less than 75% of the asking price
Reduce your store inventory to one page anytime after the 20th day
Maintain the leader position for 7 days
Auction 20 items for a profit
End a day with two or more characters liking you (in green)
End a day with Patrick Merman in a green mood
Sell 5 items from Lizzie Davis' crawl space
Change a character's mood to green in one transaction
Buy a Bigfoot Photo
Reach the Number 1 Rank!
Consult the Expert 20 times
Buy a Maffler Man
Buy and sell 20 items from the Hot Category
Make a profit 5 days in a row
Buy a Vampire Hunting Kit
Complete a hidden object scene in under a minute
Combine two items to create something new
Complete 5 unique hidden object scenes
Buy a Motorized Scooter from Hambone Richards
Restore an item
Buy and sell an item from the Hot Category