Here is the full list of all 27 POSTAL achievements. It takes around 25-30 hours to unlock all of the achievements on Windows.
Duck under a rocket.
Take a rocket to the face.
Make 100 kills.
Firebomb the band.
Run for 5 minutes.
Touch someone while burning.
Start the second level.
Perform your first execution.
Make your first kill.
Commit suicide.
Make 1000 kills.
Make 10000 kills.
Complete level 10.
Complete the game.
Fire 1,000,000 bullets.
Hit 100,000 targets.
Take 10,000 hits.
Complete the game having killed everything.
Complete the game having only killed hostiles.
Complete the game using only the M16.
Use every weapon in the game.
Complete a level with less than 10 health.
Fight an ostrich.
Watch all the credits.
Play the Mac or Linux version of the game.
Kill a naked person.
Enable cheats.