Here is the full list of all 40 Legend of Grimrock achievements. It takes around 35-40 hours to unlock all of the achievements on Windows.
Complete the game with hard difficulty setting
Find all treasures
Find all secrets
Find 5 skulls
Collect and wear full set of Valor armor (6pieces)
Open all iron doors
Mix 50 potions
Obtain level 50 in any skill
Collect and wear full set of plate mail (5 pieces)
Find Dismantler
Find the pie
Find entrance to the Vault of Dismantler
Survive the slimes
Backstab a monster
Throw a rock 100 times
Complete the game
Complete the game with old school mode
Find 50 secrets
Cast 500 spells
Get into the Prison
Give Toorum a hand
Find Zhandul's Orb
Collect and wear lurker's wardrobe (4 pieces)
Solve the Checkered room puzzle
Collect and wear full set of chitin armor (4 pieces)
Survive the invasion of white blobs
Travel 10000 tiles
Jump 25 times into a pit
Kill 250 monsters
Mix 10 potions
Perform 500 ranged weapon attacks
Kill a monster by dropping or teleporting on it
Kill your first ogre
Cast 250 Spells
Find 25 secrets
Perform 500 melee weapon attacks
Find 10 secrets
Perform 250 unarmed attacks
Cast 25 spells
Finish first level in under 4 minutes