Here is the full list of all 61 Hero's Hour achievements.
Win a game as Lament (normal or harder)
Put 200 power worth of units to work at a Slave Pens
Cast Shadowcasting while your hero has 50 or more spellpower
Win a game as Pyre (normal or harder)
Win a game as Decay (normal or harder)
Find an obelisk treasure with just 1 clue
Win a game as Arcane (normal or harder)
Control 10 overgrown mines
Win a game as Pillar (normal or harder)
Convert a town to a faction you did not start as
Complete a full artifact set
Have a hero reach level 30
Have a hero with a sum of attack, defence, knowledge and spellpower above 100
Bloodwarp a Hatchling into a Seraph
Save 500 creatures using infirmaries and hospitals in a single game
Have three artifacts in a set
Devour a Black Dragon
Defeat a challenging enemy in battle using only elementals
Have a hero with an artifact in all equipment slots
Enter combat against an enemy player with at least 2000 power worth of army
Have 100000 gold
Achieve rank 5 in a hero skill
Have a hero reach level 20
Defeat a near impossible enemy army
Win a battle without taking casualties
Learn an adventure map spell at an Archmage Tribunal
Fully develop a town
Win a Normal difficulty game
Win an Easy difficulty game
Win a game as Order (normal or harder)
Create an Idol
Acquire a treasure elemental
Win a game before week 3
Win a game in less than 15 minutes
Win a game in less than 30 minutes
Win a game without casting magic
Win a game without hiring a hero
Win a game without any artifacts
Recruit 666 Pyre units in one game
Win a 5+ player game
Win a 7-player game
Win a Challenging difficulty game
Win a Hardcore difficulty game
Win a game as Wild (normal or harder)
Win a game as Horde (normal or harder)
Win a game as Enclave (normal or harder)
Defeat the red dragon in Skirmish mode
Defeat the ghost larvae in Skirmish mode
Defeat the black dragons in Skirmish mode
Acquire a dragon via Diplomacy
Win a game as Tide (normal or harder)
Win a game as Earthen (normal or harder)
Use a Forlorn Cloister with your highest levelled hero
Enter combat with a hero that uses the most overpowered Rune
Win a game on Hardcore+ and with hamlet starting conditions
Win a game on the Patience map in less than 24 real-time hours
Encounter 95% of all rare creatures
Encounter 95% of all artifacts
Encounter 95% of all spells
Encounter 95% of all adventure buildings
Achieve 95% of all achievements