Here is the full list of all 29 Garry's Mod achievements. It takes around 200 hours to unlock all of the achievements on Windows.
Play on the same server as garry
Get 1000 thumbs on a single upload (then go to jail)
Your Workshop uploads got 1000 thumbs
You have wasted a year of your life playing GMod!
Your workshop uploads got 100 thumbs
One whole month of your life wasted
Your Workshop uploads got 10 thumbs
Play with 10 friends
Start Garry's Mod 1000 times
One whole week of your life wasted
Remove 5000 things
24 hours of your life wasted
Open the spawnmenu 100,000 times
Spawn 2000 ragdolls
Kill 1000 innocent animals
Play on the same server & map for 8 hours
Play on the same server & map for 4 hours
Spawn 5000 props
Play 20 different maps
Burst 1000 balloons
Kill 1000 friendly NPCs
Eat 200 balls
Play a gamemode that isn't sandbox
Play multiplayer at least once
Experience 500 Lua programming errors
Say the secret phrase
Killed 1000 Baddies
Spawn 1000 NPCs
Play singleplayer at least once