Here is the full list of all 29 Garry's Mod achievements. It takes around 200 hours to unlock all of the achievements on Windows.
Start Garry's Mod 1000 times
Burst 1000 balloons
Kill 1000 innocent animals
Kill 1000 friendly NPCs
Killed 1000 Baddies
Eat 200 balls
Spawn 1000 NPCs
Play 20 different maps
Your Workshop uploads got 10 thumbs
Your workshop uploads got 100 thumbs
Your Workshop uploads got 1000 thumbs
Get 1000 thumbs on a single upload (then go to jail)
Say the secret phrase
Experience 500 Lua programming errors
Play a gamemode that isn't sandbox
Play multiplayer at least once
Play singleplayer at least once
You have wasted a year of your life playing GMod!
Play with 10 friends
Play on the same server as garry
Play on the same server & map for 8 hours
Play on the same server & map for 4 hours
24 hours of your life wasted
One whole week of your life wasted
One whole month of your life wasted
Spawn 5000 props
Remove 5000 things
Open the spawnmenu 100,000 times
Spawn 2000 ragdolls