Here is the full list of all 50 Game of Thrones achievements. It takes around 20-25 hours to unlock all of the achievements on Windows.
Chapter 1: confront the four recruits during the training session with Mors
Finish Mors' Story
Gain all the skills linked to the dog with Mors
Reach the maximum level
Finish chapter 15
Finish chapter 14
Complete all the secondary objectives of the story
Chapter 14: come to the aid of the Reapers
Finish chapter 13
Send 10 recruits to the Wall with Mors
Finish chapter 12
Kill 400 enemies
Finish chapter 11
Chapter 11: bring an end to the trial by combat in under 2 minutes
Finish chapter 10
Learn all skills within a character's stance tree
Finish chapter 9
Chapter 9: suffer all the physical abuse during the torture sequence
Chapter 9: kill 6 of Lord Harlton's soldiers during the fight at dinner
Finish chapter 8
Seize the three objects of value from the Collector with Alester
Emerge triumphant in the final arena combat
Chapter 8: save Orys from the City Watch
Find 10 secrets with the vision of R'hllor
Finish chapter 7
Finish chapter 6
Finish chapter 5
Kill 10 enemies with Mors' dog in skinchanger mode
Finish chapter 4
Mete out 5 deathblows
Acquire 1 golden dragon
Finish chapter 3
Use Mors' dog's sense of smell to find 5 secret objects
Finish chapter 2
Chapter 2: protect the people with Alester
Finish chapter 1
Finish Alester's story
Chapter 2: protect the nobility with Alester
Chapter 6: don't lose pursuit of the bastard
Chapter 7: find all the corrupt brothers of the Night's Watch
Chapter 7: attack the camp without killing the sentries at the start
Chapter 8: find the key in Alester's father's tomb
Chapter 12: take back Riverspring with a total victory
Chapter 13: reach Jeyne's room without ever being seen
Chapter 15: execute the judgement passed down on the Westfords
Lose the final battle
Convince Bethany to return to Chataya's brothel with Alester
Find all the statues of the Seven
Finish the game without a single ally (except Mors and Alester) being KO'd
Gain all the skills linked to R'hllor's fire with Alester