This achievement is not that difficult but takes a lot of time. There are 23 jobs and 4 characters. I would not worry too much about grinding this until all your other achievements are done. I am currently training to battle the Iron Giant and have about 3 per character complete as well as another 2 high level jobs.
TIPS
Fight all enemies - Avoid fleeing from fights. Fight every enemy you run into and do all the extras light fighting Odin, Leviathan and Bahamut.
Know your party - If you know you will defeat a character with one or two attacks, make your other characters guard. The guard function always go first and then your attackers will finish the round getting all jobs a round towards their job level. This will help level up faster. Also knowing which characters will attack first can help as well.
Immediately change jobs when one hits lvl 99 - Dont waste valuable job level rounds by keeping a lvl 99 job equipped. The only exception would be for a boss. You probably dont want to go into a boss battle with a bunch of guys under job lvl 15. You should be fine if it is just one.
The way Job leveling works is that every action accumulates job points. To level up a job you must obtain 100 job points. You can get up to 199 per battle. For every job you get 20 job points per action(Attack, Guard, Magic, Steal, Study ect. Items, and changing formations do not earn job points.) for the first 14 levels. This means you would level up by using an action 5 times in a battle per character. After that it varies. Below is the # of actions needed for the jobs after Lvl 14:
5 Actions
Freelancer
Scholar
6 Actions
Thief
Bard
7 Actions
Dragoon
8 Actions
Warrior:
Monk :
Ranger
Geomancer
Viking
Dark Knight
Black Belt
9 Actions
Red Mage
Knight
Summoner
Ninja
10 Actions
White Mage
Black Mage
Evoker
Magus
Devout
Sage
12 Actions
Onion Knight
Once you complete the game you can go anywhere in the map to grind this. Many people use the giant forest around Ur but at that point in the game when you have completed everything, most enemies are only going to hit you for 1 damage max. Find an enemy, guard for the necessary amount of rounds and then end it by killing the enemy with your slowest Character(This is just in case you have a class that does not have the guard function) during the final round. Rinse and repeat.