Here is the full list of all 29 Garry's Mod achievements. It takes around 200 hours to unlock all of the achievements on Windows.
Spawn 2000 ragdolls
Burst 1000 balloons
Spawn 1000 NPCs
Remove 5000 things
Start Garry's Mod 1000 times
Play on the same server & map for 8 hours
Spawn 5000 props
Play with 10 friends
One whole month of your life wasted
One whole week of your life wasted
Eat 200 balls
Play 20 different maps
Play on the same server & map for 4 hours
24 hours of your life wasted
Experience 500 Lua programming errors
Play a gamemode that isn't sandbox
Play multiplayer at least once
Play singleplayer at least once
Say the secret phrase
You have wasted a year of your life playing GMod!
Killed 1000 Baddies
Play on the same server as garry
Kill 1000 innocent animals
Open the spawnmenu 100,000 times
Kill 1000 friendly NPCs
Your Workshop uploads got 10 thumbs
Your workshop uploads got 100 thumbs
Your Workshop uploads got 1000 thumbs
Get 1000 thumbs on a single upload (then go to jail)