Here is the full list of all 17 Madballs in Babo:Invasion achievements.
Host a 4-Player co-op game
Unlock the Hero Ranks
25 kills using the Striker energy mode
Crush 100 enemies using Magmor's Colossus ability
Win a 6+ player CTF game with the most points on your team
Win an 8+ player Invasion game
Play with somebody who has the Playbrains rules achievement
Unlock your first item
Finish the campaign
A fierce kill using every weapon
Find all 50 secrets in the campaign
Win 5 games of Team Skirmish
Unlock the Officer Ranks
Achieve the top Hero Rank
Play as every B*D*I class in a versus match
Play as every Scorched class in a versus match
Get over 2500 points in a skirmish match