Here is the full list of all 21 Yu-Gi-Oh! Legacy of the Duelist achievements.
Defeat 5Ds Campaign
Defeat ZEXAL Campaign
Perform a Pendulum Summon
Unlock all avatars
Win all Duelist Challenges
Deal 50k in Reflective Damage
Win an unranked multiplayer match (duel)
Win a ranked multiplayer match (duel)
Perform a Synchro Summon
Chain 100 times
Deal 100k in Effect Damage
Win a Battle Pack match (duel)
Create 5 decks
Defeat GX Campaign
Perform a Xyz Summon
Deal 200k in Direct Damage
Defeat Classic Campaign
Create your first deck
Perform a Fusion Summon
Win a duel by having all Exodia cards in hand
Perform a Tribute Summon