Here is the full list of all 40 XCOM: Chimera Squad achievements. It takes around 60-80 hours to unlock all of the achievements on Windows.
Win the campaign.
Win the campaign on Impossible difficulty.
Complete the Progeny Investigation.
Replace an Agent mid-mission with an Android.
Launch a mission with no human agents in the squad.
Capture a Sorcerer.
Use every Agent in at least one mission.
Unlock all Field Abilities.
Complete 20 Assembly Projects in a single campaign.
Fully upgrade an Android.
Have Rank 3 Field Teams in all nine districts.
Buy 20 unique Scavenger Market items in a single campaign.
Reach max rank with all Agents in a single campaign.
Complete all of one Agent’s class training.
Complete all versions of each Faction’s Takedown mission over multiple campaigns.
Complete every Spec Op at least once in a single campaign.
Use every type of Breach point.
As Godmother, activate Overtime and down an enemy on both turns.
Complete an objective with an action from Terminal’s Cooperation.
Have Kinetic Armor on all 4 squad members at once.
Use Verge to do 10 or more damage with one Mindflay.
Use Claymore to detonate a Shrapnel Bomb with another explosive.
Use Blueblood to hit 3 or more enemies with one Phase Lance shot.
Hack an enemy Android with Patchwork and trigger Self-Destruct.
Relocate the same unit with Shelter and his ghost in one turn.
Use Torque to Tongue Pull an enemy into poison.
Complete a mission with only one Agent left standing.
Complete a mission without killing a single enemy.
Complete an encounter by only dealing damage with melee attacks.
Move a VIP with Shelter’s Relocate and Torque’s Tongue Pull.
Complete the Gray Phoenix Investigation.
Equip an Epic Weapon.
Use Zephyr to hit 3 or more enemies with one use of Crowd Control.
Capture a Praetorian.
Have 8 Agents in the squad in a single campaign.
Complete the Sacred Coil Investigation.
Capture a Ronin.
Kill an enemy with Axiom while Berserk.
Clear an entire encounter during the Breach turn.
Complete the tutorial.