Here is the full list of all 29 Worms W.M.D achievements.
Get 80 kills in a Helicopter
Fully customise a team of worms
Complete all Challenges
Complete the Campaign
Complete 5 Challenges
Kill 500 worms
Gain a Gold Medal on all Training levels
Complete 40 Sub Goals
Complete 15 Campaign Missions
Get 40 kills using a Mounted Gun
Craft 30 weapons across all game modes
Win an Online game with all worms in Buildings
Play a Ranked Match
Complete all Training levels
Complete all the Basic Training levels
Collect a wanted poster
Kill 4 worms in a single turn
Complete Navigation Training
Finish a game with a worm on more health than it started with
Craft every weapon in the game
Kill 20 worms with Prod
Reach Sheep Rank
Get 80 kills in a Tank
Get 80 kills in a Mech
Play 50 Online Multiplayer Games
Win an online multiplayer match in Sudden Death
Win 3 online games in a row
Complete all the Sub Goals
Unlock all the Customisation Items