Here is the full list of all 100 Warhammer Age of Sigmar: Champions achievements.
Reach level 30
Reach Destruction alliance level 10
Win a game without playing abilities
Play 100 Unaligned Cards
Win 10 Games
Play 100 Order cards
Reach Chaos alliance level 5
Reach level 20
Play 100 Destruction cards
Win 5 Games
Reach Destruction alliance level 5
Reach Death alliance level 5
Defeat 1 AI Challenger
Reach Order alliance level 5
Reach level 10
Play 10 Games
Play 20 Death cards
Play 20 Destruction cards
Play 20 Order cards
Play 20 Chaos cards
Play 20 Unaligned Cards
Play 5 Games
Win 1 Game
Play 3 Games
Reach level 5
Play 1 Game
Complete 1 Campaign
Complete 5 Campaigns
Complete 10 Campaigns
Complete 25 Campaigns
Complete 50 Campaigns
Complete 75 Campaigns
Complete 100 Campaigns
Complete 250 Campaigns
Complete 500 Campaigns
Defeat the Final Boss of a Campaign with a Chaos Deck
Defeat the Final Boss of a Campaign with a Death Deck
Defeat the Final Boss of a Campaign with a Destruction Deck
Defeat the Final Boss of a Campaign with 35 health remaining
Defeat the Final Boss of a Campaign with an Order Deck
Complete 5 different Campaigns
Complete 10 different Campaigns
Reach Chaos alliance level 10
Reach Chaos alliance level 20
Reach Chaos alliance level 50
Play 100 Chaos cards
Play 1000 Chaos cards
Play 10000 Chaos cards
Reach Death alliance level 10
Reach Death alliance level 20
Reach Death alliance level 50
Play 100 Death cards
Play 1000 Death cards
Play 10000 Death cards
Reach Destruction alliance level 20
Reach Destruction alliance level 50
Play 1000 Destruction cards
Play 10000 Destruction cards
Reach Order alliance level 10
Reach Order alliance level 20
Reach Order alliance level 50
Play 1000 Order cards
Play 10000 Order cards
Win 1 game with 0 health remaining
Defeat 5 Different AI Challengers
Defeat 10 Different AI Challengers
Defeat 15 Different AI Challengers
Win 1 Ranked Game
Win 5 Ranked Games
Win 10 Ranked Games
Win 100 Ranked Games
Win 1000 Ranked Games
Win 10000 Ranked Games
Win 1 game with 35 health remaining
Win 1 game with no cards left in your deck
Win 1 game with 1 health remaining
Play a Ranked Game
Defeat 5 AI Challengers
Defeat 10 AI Challengers
Defeat 25 AI Challengers
Defeat 50 AI Challengers
Defeat 75 AI Challengers
Defeat 100 AI Challengers
Win 100 Games
Win 1000 Games
Win 10000 Games
Win a game without playing spells
Win a game without playing units
Reach level 20 in all Alliances
Reach level 50 in all Alliances
Reach level 40
Reach level 50
Reach level 75
Reach level 100
Reach level 200
Reach level 300
Reach level 400
Reach level 500
Play 1000 Unaligned Cards
Play 10000 Unaligned Cards