Here is the full list of all 36 Valkyria Chronicles 4 achievements. It takes around 60-80 hours to unlock all of the achievements on Windows.
Obtained all achievements.
Triggered a Last Stand 15 times.
Obtained all decorations.
Obtained all infantry weapons.
Watched all event scenes.
Obtained A ranks on all missions.
Gave direct commands 15 times.
Obtained all tank parts.
Recruited all squad members.
Gave ship orders 15 times.
Kept your promise with Riley Miller.
Rescued 10 allies in critical condition.
Obtained all ship parts.
All of your classes were upgraded to max level.
Defeated 1000 enemy units.
Learned all orders.
Completed a squad story for the first time.
One of your classes was promoted to Paragon status.
Completed Chapter 17, and witnessed the end of the war.
Completed Chapter 18, and ended Belgar's dark ambitions.
Completed Chapter 15, and defeated both Walz and Crymaria.
Completed Chapter 11, and made it past the Sea Fortress.
Defeated 15 enemy aces.
Gave orders 15 times.
Earned 1,000,000 DCT cumulatively.
Obtained A ranks on 20 missions.
Developed the Hafen into a heavy tank.
Completed Chapter 7, and rendezvoused with the Centurion.
One of your classes was promoted to Elite status.
Completed Chapter 4, and won the battle of Siegval.
Completed 10 missions without anyone in critical condition.
Defeated an enemy ace for the first time.
One of your squadmates was promoted to Corporal.
Learned an order at the Mess Hall for the first time.
Used R&D Facility for the first time.
Obtained an A rank on a mission for the first time.