Here is the full list of all 36 Valkyria Chronicles 4 achievements. It takes around 60-80 hours to unlock all of the achievements on Windows.
Obtained all achievements.
Obtained all decorations.
Obtained all infantry weapons.
Triggered a Last Stand 15 times.
Obtained all tank parts.
All of your classes were upgraded to max level.
Watched all event scenes.
Obtained A ranks on all missions.
Gave ship orders 15 times.
Gave direct commands 15 times.
Defeated 1000 enemy units.
Obtained all ship parts.
Recruited all squad members.
Kept your promise with Riley Miller.
One of your classes was promoted to Paragon status.
Completed Chapter 18, and ended Belgar's dark ambitions.
Completed Chapter 17, and witnessed the end of the war.
Learned all orders.
Completed Chapter 15, and defeated both Walz and Crymaria.
Rescued 10 allies in critical condition.
Defeated 15 enemy aces.
Completed Chapter 11, and made it past the Sea Fortress.
Completed a squad story for the first time.
Earned 1,000,000 DCT cumulatively.
Obtained A ranks on 20 missions.
Gave orders 15 times.
Developed the Hafen into a heavy tank.
Completed Chapter 7, and rendezvoused with the Centurion.
One of your classes was promoted to Elite status.
Completed 10 missions without anyone in critical condition.
Completed Chapter 4, and won the battle of Siegval.
One of your squadmates was promoted to Corporal.
Learned an order at the Mess Hall for the first time.
Defeated an enemy ace for the first time.
Used R&D Facility for the first time.
Obtained an A rank on a mission for the first time.