Here is the full list of all 36 Valkyria Chronicles 4 achievements. It takes around 60-80 hours to unlock all of the achievements on Windows.
Obtained all achievements.
Obtained all decorations.
Rescued 10 allies in critical condition.
Triggered a Last Stand 15 times.
Watched all event scenes.
Obtained all infantry weapons.
Obtained A ranks on all missions.
All of your classes were upgraded to max level.
Obtained all tank parts.
Recruited all squad members.
Obtained all ship parts.
Kept your promise with Riley Miller.
One of your classes was promoted to Paragon status.
Completed Chapter 18, and ended Belgar's dark ambitions.
Completed Chapter 17, and witnessed the end of the war.
Learned all orders.
Gave ship orders 15 times.
Completed Chapter 15, and defeated both Walz and Crymaria.
Defeated 1000 enemy units.
Completed Chapter 11, and made it past the Sea Fortress.
Gave direct commands 15 times.
Earned 1,000,000 DCT cumulatively.
Developed the Hafen into a heavy tank.
Defeated 15 enemy aces.
Completed Chapter 7, and rendezvoused with the Centurion.
Obtained A ranks on 20 missions.
Gave orders 15 times.
One of your classes was promoted to Elite status.
Completed Chapter 4, and won the battle of Siegval.
Completed a squad story for the first time.
Completed 10 missions without anyone in critical condition.
One of your squadmates was promoted to Corporal.
Defeated an enemy ace for the first time.
Learned an order at the Mess Hall for the first time.
Used R&D Facility for the first time.
Obtained an A rank on a mission for the first time.