Here is the full list of all 36 Valkyria Chronicles 4 achievements. It takes around 60-80 hours to unlock all of the achievements on Windows.
Obtained all achievements.
Triggered a Last Stand 15 times.
Obtained all decorations.
Obtained all infantry weapons.
All of your classes were upgraded to max level.
Gave ship orders 15 times.
Obtained all tank parts.
Obtained A ranks on all missions.
Watched all event scenes.
Obtained all ship parts.
Recruited all squad members.
Defeated 1000 enemy units.
Rescued 10 allies in critical condition.
Kept your promise with Riley Miller.
One of your classes was promoted to Paragon status.
Completed Chapter 18, and ended Belgar's dark ambitions.
Learned all orders.
Completed Chapter 17, and witnessed the end of the war.
Gave direct commands 15 times.
Completed Chapter 15, and defeated both Walz and Crymaria.
Gave orders 15 times.
Completed Chapter 11, and made it past the Sea Fortress.
Earned 1,000,000 DCT cumulatively.
Defeated 15 enemy aces.
Completed a squad story for the first time.
Obtained A ranks on 20 missions.
Developed the Hafen into a heavy tank.
One of your classes was promoted to Elite status.
Completed Chapter 7, and rendezvoused with the Centurion.
Completed 10 missions without anyone in critical condition.
Completed Chapter 4, and won the battle of Siegval.
One of your squadmates was promoted to Corporal.
Defeated an enemy ace for the first time.
Learned an order at the Mess Hall for the first time.
Used R&D Facility for the first time.
Obtained an A rank on a mission for the first time.