Here is the full list of all 44 Underhero achievements.
You deserve a raise
All Music Cassettes
Defeated ???
Defeated Mr. Stitches
The End of The World
Spared the Masked Children in Heroes Road
All HP Upgrades!
Bribed 20 Enemies
All weapon Upgrades!
Recruited The Baron
Recruited the Moth Queen
Eased a Fathers Mind
All missing keys used
Defeated T. Bur
The Show must go on
Read all Robot Text Logs
Night Theater
All Shield Upgrades
Complete Jilani'snPepper Collection
Defeated El Salserissimo
Cook the spiciest salsa
Half HP Upgrades!
Half Music Cassettes
Found the Hidden Treasure of the beach
Cleared the Pica Pica Coliseum
Half weapon Upgrades!
Defeated Baron van Gregory
Won the Ice Skating Competition
Defeated The Grey Kid
You gave Blobber his favorite drink
Completed the Bros Quest
Made your first drink
First Shield Upgrade
Defeated The Moth Queen, Alexandria II
First missing key used
A tree full of beer
First weapon Upgrade!
Killed 20 Enemies
First HP Upgrade!
Won the Ant's Gang Race
Your First Bribe
First Music Cassette
Killed your First Enemy in Combat
Finish the Intro