Here is the full list of all 30 Top Villain: Total Domination achievements.
Defeat your archenemy!
Kill your archenemy!
Begin planning to take over the world!
Settle the Henchmen Strike!
Make Dr. Glass Frog incredibly angry.
Get rid of Dr. Glass Frog forever.
Sway Dr. Glass Frog to your side.
Survive your visit to Villain-Con.
Survive your fight with the California Condor.
Have your big interview with Whitney Wang.
Escape your lair with your Doomsday Weapon intact.
Take no damage at all.
Refuse to meet with the Conspirator.
Beat the entire game without any powers.