Here is the full list of all 46 The King of Fighters XIII Steam Edition achievements.
Play 300 [ranked matches / player matches]
Win 100 [ranked matches / player matches]
Perform 50 Drive Cancels (Arcade, Versus)
Get 10 consecutive wins in a ranked match
Play 100 [ranked matches / player matches]
Win 50 [ranked matches / player matches]
Hit 100 times using Super Special Moves (Arcade, Versus)
Play 50 [ranked matches / player matches]
Clear ARCADE MODE on VERY HARD
Win 25 [ranked matches / player matches]
Get 5 consecutive wins in a ranked match
Create 10 characters in Customize
Create 10 rooms
Be challenged by "Saiki" and win in ARCADE
Clear ARCADE MODE without continuing
Hit 100 times using EX Special Moves (Arcade, Versus)
Perform 10 Perfect Victories (Arcade, Versus)
Clear Time Attack mode for the first time
Defeat 3 characters in Survival mode
Get 2 consecutive wins in a ranked match
Get 10 straight wins (Arcade, Versus)
Clear STORY.
Be challenged by "Ash" and win in ARCADE
Get an SS at the victory screen
Hit 100 times using Special Moves (Arcade, Versus)
Be challenged by "Billy" and win in ARCADE
Perform 10 Target Actions (Arcade)
Get an S at the victory screen
Win 5 [ranked matches / player matches]
Win your first [ranked match / player match]
Register an icon, team and message in Customize
Complete the tutorial
Play your first [ranked match / player match]
Complete STORY.
Perform 300 Target Actions (Arcade)
Hit 100 times using EX Super Special Moves (Arcade, Versus)
Hit 100 times using NEO MAX Super Special Moves (Arcade, Versus)
Perform 50 Super Special Moves Finishes (Arcade, Versus)
Get 50 NEO MAX Super Special Moves Finishes (Arcade, Versus)
Perform 50 Super Cancels (Arcade, Versus)
Perform 50 HD Cancels (Arcade, Versus)
Perform 50 MAX Cancels (Arcade, Versus)
Clear Time Attack mode with 30 characters
Defeat 35 characters in Survival mode
Complete all trials for 1 character in Trial mode
Clear 200 trials in Trial mode