Here is the full list of all 46 The King of Fighters XIII Steam Edition achievements.
Complete STORY.
Win 50 [ranked matches / player matches]
Play 100 [ranked matches / player matches]
Play 50 [ranked matches / player matches]
Perform 50 HD Cancels (Arcade, Versus)
Perform 50 Drive Cancels (Arcade, Versus)
Perform 50 Super Cancels (Arcade, Versus)
Win 25 [ranked matches / player matches]
Hit 100 times using EX Super Special Moves (Arcade, Versus)
Get 50 NEO MAX Super Special Moves Finishes (Arcade, Versus)
Defeat 35 characters in Survival mode
Clear Time Attack mode for the first time
Clear ARCADE MODE on VERY HARD
Hit 100 times using NEO MAX Super Special Moves (Arcade, Versus)
Get 10 consecutive wins in a ranked match
Win 5 [ranked matches / player matches]
Get 5 consecutive wins in a ranked match
Get 2 consecutive wins in a ranked match
Win your first [ranked match / player match]
Clear ARCADE MODE without continuing
Get an SS at the victory screen
Be challenged by "Saiki" and win in ARCADE
Perform 50 Super Special Moves Finishes (Arcade, Versus)
Hit 100 times using EX Special Moves (Arcade, Versus)
Hit 100 times using Super Special Moves (Arcade, Versus)
Perform 10 Perfect Victories (Arcade, Versus)
Be challenged by "Ash" and win in ARCADE
Play your first [ranked match / player match]
Create 10 rooms
Defeat 3 characters in Survival mode
Create 10 characters in Customize
Register an icon, team and message in Customize
Complete the tutorial
Clear STORY.
Get 10 straight wins (Arcade, Versus)
Hit 100 times using Special Moves (Arcade, Versus)
Be challenged by "Billy" and win in ARCADE
Get an S at the victory screen
Perform 10 Target Actions (Arcade)
Perform 300 Target Actions (Arcade)
Perform 50 MAX Cancels (Arcade, Versus)
Clear Time Attack mode with 30 characters
Complete all trials for 1 character in Trial mode
Clear 200 trials in Trial mode
Play 300 [ranked matches / player matches]
Win 100 [ranked matches / player matches]