Here is the full list of all 31 Square Heroes achievements.
Play entire round without dying (3+ players)
Win 5 games in a row
Complete Tutorial
Score three Kill Streaks in a match
Score Multi Kill
Host an Internet game with remote players
Win team game 4+ players with 75% or more of team score
Score two Kill Streaks in a match
Re-gen your health twice over
Score a Kill Streak
Score Double Kill
Score First Kill
Survive Survival!
Kill with Proximity Mine
Kill with Laser and Machine in round
Host 20 Internet games with remote players
Score Mega Kill
Re-gen 200% Team health
Replenish 150% Team ammo
Win DM using only Explosives (3+ players)
Capture Gnome opponent almost captured
Complete 5 LAN games
Complete 100 games
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Kill with Cross-bow and Harpoon
Kill opponent with Nuke Bag
Win without anyone else scoring (3+ players)
Kill with Fire! (Flamethrower and Molotov)
Earn all other Achievements
Capture 15 Gnomes
Score Devastation