Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Complete game on "FUBAR" difficulty.
Complete game on "Suicide Mission" difficulty.
Recover all Intel Items.
Kill an oryx. (campaign only)
Play it smart.
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Live and let die.
You are relieved.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Choose restraint.
Show mercy.
Follow your orders.
Kill 50 enemies with grenades. (campaign only)
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Kill 75 enemies with any shotgun. (campaign only)
Complete three chapters in a row without being killed or reloading a checkpoint.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Live and let live.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
Carry on, soldier.
The end of the line.
Recover 12 Intel Items.
Choose vengeance.
Kill 5 enemies using blind fire. (campaign only)
Get out of here!
Kill 150 enemies with any heavy weapon. (campaign only)
Hit 10 enemies with your melee attack. (campaign only)
Stand united.
Kick an enemy by vaulting over a cover. (campaign only)
Save a bullet.
Kill 50 enemies with any sniper rifle. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Stun an enemy by dumping sand on their head. (campaign only)
Buck the chain of command.
Kill 350 enemies with any rifle. (campaign only)
Play it loose.
Kill 250 enemies with headshots. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
Sprint into cover 10 times while under fire. (campaign only)
Face the horrors of war.
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Engineer an exit strategy.
We have contact.
Recover one Intel Item.
Look out below.
Kill 3 enemies with a single grenade. (campaign only)
What's lost is found.