Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
You are relieved.
Recover all Intel Items.
Play it loose.
Recover 12 Intel Items.
Complete three chapters in a row without being killed or reloading a checkpoint.
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Live and let die.
Complete game on "FUBAR" difficulty.
Choose vengeance.
Kill 50 enemies with any sniper rifle. (campaign only)
Kill an oryx. (campaign only)
Save a bullet.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Follow your orders.
Kill 75 enemies with any shotgun. (campaign only)
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Kill 150 enemies with any heavy weapon. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Live and let live.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
Complete game on "Suicide Mission" difficulty.
Carry on, soldier.
The end of the line.
Choose restraint.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Kill 50 enemies with grenades. (campaign only)
Get out of here!
Kill 250 enemies with headshots. (campaign only)
Stand united.
Hit 10 enemies with your melee attack. (campaign only)
Kick an enemy by vaulting over a cover. (campaign only)
Show mercy.
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Kill 350 enemies with any rifle. (campaign only)
Stun an enemy by dumping sand on their head. (campaign only)
Buck the chain of command.
Play it smart.
Face the horrors of war.
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Kill 3 enemies with a single grenade. (campaign only)
Kill 5 enemies using blind fire. (campaign only)
Sprint into cover 10 times while under fire. (campaign only)
Engineer an exit strategy.
We have contact.
Kill an enemy just as they are throwing a grenade. (campaign only)
Look out below.
What's lost is found.
Recover one Intel Item.