Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Complete three chapters in a row without being killed or reloading a checkpoint.
Complete game on "FUBAR" difficulty.
Play it smart.
Recover all Intel Items.
Kill an oryx. (campaign only)
Complete game on "Suicide Mission" difficulty.
You are relieved.
Choose restraint.
Kick an enemy by vaulting over a cover. (campaign only)
Save a bullet.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Kill 150 enemies with any heavy weapon. (campaign only)
Hit 10 enemies with your melee attack. (campaign only)
Kill 75 enemies with any shotgun. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Follow your orders.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Kill 50 enemies with grenades. (campaign only)
Sprint into cover 10 times while under fire. (campaign only)
Live and let live.
Live and let die.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
Carry on, soldier.
The end of the line.
Kill 5 enemies using blind fire. (campaign only)
Choose vengeance.
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Get out of here!
Kill 100 enemies with any pistol or SMG. (campaign only)
Kill 50 enemies with any sniper rifle. (campaign only)
Recover 12 Intel Items.
Stand united.
Kill 250 enemies with headshots. (campaign only)
Show mercy.
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Stun an enemy by dumping sand on their head. (campaign only)
Kill 350 enemies with any rifle. (campaign only)
Buck the chain of command.
Play it loose.
Kill 3 enemies with a single grenade. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
Face the horrors of war.
Engineer an exit strategy.
We have contact.
Look out below.
Recover one Intel Item.
What's lost is found.