Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Complete game on "FUBAR" difficulty.
Recover all Intel Items.
Kill an oryx. (campaign only)
Live and let die.
Complete game on "Combat Op" difficulty.
Complete game on "Suicide Mission" difficulty.
You are relieved.
Choose vengeance.
Save a bullet.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Follow your orders.
Play it loose.
Kill 50 enemies using only the Attack Command. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
Kill 75 enemies with any shotgun. (campaign only)
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Live and let live.
Complete game on "Walk on the Beach" difficulty.
Carry on, soldier.
The end of the line.
Choose restraint.
Recover 12 Intel Items.
Kill 250 enemies with headshots. (campaign only)
Kill 150 enemies with any heavy weapon. (campaign only)
Get out of here!
Hit 10 enemies with your melee attack. (campaign only)
Stand united.
Kill 350 enemies with any rifle. (campaign only)
Kill 50 enemies with any sniper rifle. (campaign only)
Kick an enemy by vaulting over a cover. (campaign only)
Show mercy.
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Kill 50 enemies with grenades. (campaign only)
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Buck the chain of command.
Play it smart.
Stun an enemy by dumping sand on their head. (campaign only)
Face the horrors of war.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Engineer an exit strategy.
Complete three chapters in a row without being killed or reloading a checkpoint.
Sprint into cover 10 times while under fire. (campaign only)
Kill 5 enemies using blind fire. (campaign only)
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
We have contact.
Look out below.
Kill 3 enemies with a single grenade. (campaign only)
Recover one Intel Item.
What's lost is found.