Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Recover all Intel Items.
Complete game on "FUBAR" difficulty.
Stun an enemy by dumping sand on their head. (campaign only)
Kill 150 enemies with any heavy weapon. (campaign only)
Recover 12 Intel Items.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Complete three chapters in a row without being killed or reloading a checkpoint.
Kill 75 enemies with any shotgun. (campaign only)
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Kill 50 enemies using only the Attack Command. (campaign only)
Kill an oryx. (campaign only)
Live and let die.
You are relieved.
Choose vengeance.
Kill 50 enemies with grenades. (campaign only)
Save a bullet.
Buck the chain of command.
Play it loose.
Live and let live.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
Complete game on "Suicide Mission" difficulty.
Carry on, soldier.
The end of the line.
Choose restraint.
Hit 10 enemies with your melee attack. (campaign only)
Get out of here!
Kill 50 enemies with any sniper rifle. (campaign only)
Stand united.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Kick an enemy by vaulting over a cover. (campaign only)
Show mercy.
Sprint into cover 10 times while under fire. (campaign only)
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Follow your orders.
Play it smart.
Kill 350 enemies with any rifle. (campaign only)
Face the horrors of war.
Kill 250 enemies with headshots. (campaign only)
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Engineer an exit strategy.
Kill 100 enemies with any pistol or SMG. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
We have contact.
Look out below.
Kill 3 enemies with a single grenade. (campaign only)
Kill 5 enemies using blind fire. (campaign only)
What's lost is found.
Recover one Intel Item.