Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Complete game on "FUBAR" difficulty.
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Choose vengeance.
Save a bullet.
Buck the chain of command.
Play it smart.
Complete three chapters in a row without being killed or reloading a checkpoint.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Recover all Intel Items.
Kill 75 enemies with any shotgun. (campaign only)
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Kill an oryx. (campaign only)
Live and let die.
Live and let live.
Carry on, soldier.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
Complete game on "Suicide Mission" difficulty.
You are relieved.
The end of the line.
Kill 150 enemies with any heavy weapon. (campaign only)
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Choose restraint.
Kill 50 enemies with grenades. (campaign only)
Get out of here!
Hit 10 enemies with your melee attack. (campaign only)
Kick an enemy by vaulting over a cover. (campaign only)
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Recover 12 Intel Items.
Stun an enemy by dumping sand on their head. (campaign only)
Stand united.
Kill 250 enemies with headshots. (campaign only)
Kill 50 enemies with any sniper rifle. (campaign only)
Show mercy.
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Kill 350 enemies with any rifle. (campaign only)
Follow your orders.
Play it loose.
Face the horrors of war.
Kill 3 enemies with a single grenade. (campaign only)
Sprint into cover 10 times while under fire. (campaign only)
Engineer an exit strategy.
Kill 5 enemies using blind fire. (campaign only)
We have contact.
Recover one Intel Item.
Kill an enemy just as they are throwing a grenade. (campaign only)
Look out below.
What's lost is found.