Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Play it smart.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Complete three chapters in a row without being killed or reloading a checkpoint.
Kill an oryx. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Live and let live.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
Carry on, soldier.
The end of the line.
Recover 12 Intel Items.
Kick an enemy by vaulting over a cover. (campaign only)
Choose restraint.
Kill 100 enemies with any pistol or SMG. (campaign only)
Get out of here!
Kill 50 enemies with grenades. (campaign only)
Kill 75 enemies with any shotgun. (campaign only)
Kill 50 enemies with any sniper rifle. (campaign only)
Hit 10 enemies with your melee attack. (campaign only)
Stand united.
Kill 250 enemies with headshots. (campaign only)
Show mercy.
Kill 150 enemies with any heavy weapon. (campaign only)
Kill 350 enemies with any rifle. (campaign only)
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Buck the chain of command.
Play it loose.
Stun an enemy by dumping sand on their head. (campaign only)
Face the horrors of war.
Kill 3 enemies with a single grenade. (campaign only)
Engineer an exit strategy.
We have contact.
Kill an enemy just as they are throwing a grenade. (campaign only)
Look out below.
Kill 5 enemies using blind fire. (campaign only)
Recover one Intel Item.
What's lost is found.
Follow your orders.
Save a bullet.
Choose vengeance.
Complete game on "Suicide Mission" difficulty.
Sprint into cover 10 times while under fire. (campaign only)
Recover all Intel Items.
Complete game on "FUBAR" difficulty.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
You are relieved.
Live and let die.