Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Kill 150 enemies with any heavy weapon. (campaign only)
Kill 350 enemies with any rifle. (campaign only)
Live and let die.
Live and let live.
Carry on, soldier.
Complete game on "Walk on the Beach" difficulty.
You are relieved.
The end of the line.
Sprint into cover 10 times while under fire. (campaign only)
Choose vengeance.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
Kill 50 enemies with grenades. (campaign only)
Get out of here!
Recover 12 Intel Items.
Stand united.
Show mercy.
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Stun an enemy by dumping sand on their head. (campaign only)
Follow your orders.
Complete three chapters in a row without being killed or reloading a checkpoint.
Play it loose.
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Face the horrors of war.
Kick an enemy by vaulting over a cover. (campaign only)
Engineer an exit strategy.
Hit 10 enemies with your melee attack. (campaign only)
We have contact.
Kill 5 enemies using blind fire. (campaign only)
Look out below.
Kill 3 enemies with a single grenade. (campaign only)
Recover one Intel Item.
What's lost is found.
Play it smart.
Buck the chain of command.
Save a bullet.
Choose restraint.
Complete game on "Combat Op" difficulty.
Complete game on "Suicide Mission" difficulty.
Kill 100 enemies with any pistol or SMG. (campaign only)
Kill 75 enemies with any shotgun. (campaign only)
Kill 50 enemies with any sniper rifle. (campaign only)
Kill 250 enemies with headshots. (campaign only)
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Recover all Intel Items.
Complete game on "FUBAR" difficulty.
Kill an oryx. (campaign only)
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)