Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Buck the chain of command.
Live and let live.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
Carry on, soldier.
The end of the line.
Kill 150 enemies with any heavy weapon. (campaign only)
Choose vengeance.
Get out of here!
Recover 12 Intel Items.
Kill 50 enemies with any sniper rifle. (campaign only)
Stand united.
Kill 75 enemies with any shotgun. (campaign only)
Kick an enemy by vaulting over a cover. (campaign only)
Show mercy.
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Stun an enemy by dumping sand on their head. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Follow your orders.
Play it smart.
Kill 50 enemies with grenades. (campaign only)
Face the horrors of war.
Sprint into cover 10 times while under fire. (campaign only)
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Hit 10 enemies with your melee attack. (campaign only)
Engineer an exit strategy.
Kill 5 enemies using blind fire. (campaign only)
We have contact.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
Look out below.
Kill 3 enemies with a single grenade. (campaign only)
Recover one Intel Item.
What's lost is found.
Play it loose.
Save a bullet.
Choose restraint.
Complete game on "Suicide Mission" difficulty.
Kill 350 enemies with any rifle. (campaign only)
Kill 250 enemies with headshots. (campaign only)
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Complete three chapters in a row without being killed or reloading a checkpoint.
Recover all Intel Items.
Complete game on "FUBAR" difficulty.
Kill an oryx. (campaign only)
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
You are relieved.
Live and let die.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)