Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Play it smart.
Follow your orders.
Show mercy.
Choose restraint.
Complete game on "Combat Op" difficulty.
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Hit 10 enemies with your melee attack. (campaign only)
Stun an enemy by dumping sand on their head. (campaign only)
You are relieved.
Live and let die.
Live and let live.
Complete game on "Walk on the Beach" difficulty.
Carry on, soldier.
The end of the line.
Kill 350 enemies with any rifle. (campaign only)
Kill 75 enemies with any shotgun. (campaign only)
Choose vengeance.
Kill 250 enemies with headshots. (campaign only)
Get out of here!
Kill 50 enemies with grenades. (campaign only)
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Kill 150 enemies with any heavy weapon. (campaign only)
Stand united.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Kick an enemy by vaulting over a cover. (campaign only)
Save a bullet.
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Sprint into cover 10 times while under fire. (campaign only)
Recover 12 Intel Items.
Buck the chain of command.
Play it loose.
Kill 50 enemies with any sniper rifle. (campaign only)
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Face the horrors of war.
Kill 3 enemies with a single grenade. (campaign only)
Engineer an exit strategy.
Kill 5 enemies using blind fire. (campaign only)
We have contact.
Complete three chapters in a row without being killed or reloading a checkpoint.
Kill an enemy just as they are throwing a grenade. (campaign only)
Look out below.
What's lost is found.
Recover one Intel Item.
Complete game on "Suicide Mission" difficulty.
Kill 50 enemies using only the Attack Command. (campaign only)
Recover all Intel Items.
Complete game on "FUBAR" difficulty.
Kill an oryx. (campaign only)