Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Kill 50 enemies with grenades. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Live and let die.
Save a bullet.
Kill an oryx. (campaign only)
Follow your orders.
Play it smart.
Kill 50 enemies with any sniper rifle. (campaign only)
Hit 10 enemies with your melee attack. (campaign only)
Kill 75 enemies with any shotgun. (campaign only)
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Complete three chapters in a row without being killed or reloading a checkpoint.
Recover all Intel Items.
Live and let live.
Carry on, soldier.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
Complete game on "Suicide Mission" difficulty.
You are relieved.
The end of the line.
Kill 150 enemies with any heavy weapon. (campaign only)
Choose vengeance.
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Kill 250 enemies with headshots. (campaign only)
Get out of here!
Stand united.
Show mercy.
Kill 100 enemies with any pistol or SMG. (campaign only)
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Kill 350 enemies with any rifle. (campaign only)
Kill 5 enemies using blind fire. (campaign only)
Buck the chain of command.
Recover 12 Intel Items.
Play it loose.
Face the horrors of war.
Kill 3 enemies with a single grenade. (campaign only)
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Engineer an exit strategy.
Sprint into cover 10 times while under fire. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
We have contact.
Look out below.
What's lost is found.
Recover one Intel Item.
Choose restraint.
Complete game on "FUBAR" difficulty.
Stun an enemy by dumping sand on their head. (campaign only)
Kick an enemy by vaulting over a cover. (campaign only)