Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Complete three chapters in a row without being killed or reloading a checkpoint.
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Choose restraint.
Buck the chain of command.
Play it smart.
Live and let live.
Live and let die.
Carry on, soldier.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
You are relieved.
The end of the line.
Kill 150 enemies with any heavy weapon. (campaign only)
Choose vengeance.
Recover 12 Intel Items.
Get out of here!
Stand united.
Stun an enemy by dumping sand on their head. (campaign only)
Show mercy.
Kill an oryx. (campaign only)
Save a bullet.
Kick an enemy by vaulting over a cover. (campaign only)
Follow your orders.
Kill 50 enemies with grenades. (campaign only)
Kill 75 enemies with any shotgun. (campaign only)
Kill 5 enemies using blind fire. (campaign only)
Kill 50 enemies with any sniper rifle. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Play it loose.
Kill 350 enemies with any rifle. (campaign only)
Kill 250 enemies with headshots. (campaign only)
Kill an enemy by tagging him with a sticky grenade. (campaign only)
We have contact.
Engineer an exit strategy.
Face the horrors of war.
Sprint into cover 10 times while under fire. (campaign only)
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Hit 10 enemies with your melee attack. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
Look out below.
Kill 3 enemies with a single grenade. (campaign only)
Recover one Intel Item.
What's lost is found.
Complete game on "Suicide Mission" difficulty.
Recover all Intel Items.
Complete game on "FUBAR" difficulty.