Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Live and let die.
Live and let live.
Complete game on "FUBAR" difficulty.
Carry on, soldier.
Recover all Intel Items.
Choose vengeance.
Show mercy.
Stun an enemy by dumping sand on their head. (campaign only)
Follow your orders.
Play it smart.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Complete three chapters in a row without being killed or reloading a checkpoint.
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Hit 10 enemies with your melee attack. (campaign only)
Kill an oryx. (campaign only)
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
Complete game on "Suicide Mission" difficulty.
You are relieved.
The end of the line.
Kill 50 enemies with grenades. (campaign only)
Choose restraint.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Get out of here!
Kill 350 enemies with any rifle. (campaign only)
Kill 150 enemies with any heavy weapon. (campaign only)
Stand united.
Kick an enemy by vaulting over a cover. (campaign only)
Save a bullet.
Kill 250 enemies with headshots. (campaign only)
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Recover 12 Intel Items.
Kill 75 enemies with any shotgun. (campaign only)
Buck the chain of command.
Kill 50 enemies using only the Attack Command. (campaign only)
Kill 5 enemies using blind fire. (campaign only)
Play it loose.
Kill 50 enemies with any sniper rifle. (campaign only)
Face the horrors of war.
Sprint into cover 10 times while under fire. (campaign only)
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Engineer an exit strategy.
Kill an enemy just as they are throwing a grenade. (campaign only)
We have contact.
Look out below.
Kill 3 enemies with a single grenade. (campaign only)
What's lost is found.
Recover one Intel Item.