Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Kill 50 enemies with any sniper rifle. (campaign only)
Recover all Intel Items.
Buck the chain of command.
Play it smart.
Complete three chapters in a row without being killed or reloading a checkpoint.
You are relieved.
Live and let die.
Live and let live.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
Complete game on "Suicide Mission" difficulty.
Carry on, soldier.
The end of the line.
Kill 50 enemies using only the Attack Command. (campaign only)
Choose vengeance.
Choose restraint.
Kill 75 enemies with any shotgun. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Kill 50 enemies with grenades. (campaign only)
Kill 350 enemies with any rifle. (campaign only)
Get out of here!
Kill 250 enemies with headshots. (campaign only)
Recover 12 Intel Items.
Stand united.
Kill an oryx. (campaign only)
Save a bullet.
Show mercy.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Kill 150 enemies with any heavy weapon. (campaign only)
Kick an enemy by vaulting over a cover. (campaign only)
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Stun an enemy by dumping sand on their head. (campaign only)
Hit 10 enemies with your melee attack. (campaign only)
Follow your orders.
Play it loose.
Face the horrors of war.
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Kill 3 enemies with a single grenade. (campaign only)
Engineer an exit strategy.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
We have contact.
Sprint into cover 10 times while under fire. (campaign only)
Look out below.
Kill 5 enemies using blind fire. (campaign only)
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Recover one Intel Item.
What's lost is found.
Complete game on "FUBAR" difficulty.