Here is the full list of all 49 Sonic Generations Collection achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Played Time Attack on all stages.
Got all collectibles.
Got all custom skills.
Got all Red Star Rings.
Took no damage while defeating the final boss.
Got Rank S in all acts.
Got Rank S in acts 12 times.
Cleared CHEMICAL PLANT without entering the water.
Cleared all the missions.
Completed all of Sonic's friends' Challenges.
Cleared Sonic Generations.
Chatted with all of Sonic's friends you saved.
Found the spring hidden in GREEN HILL Act 1 and reached the goal with a Red Star Ring.
Cleared Green Hill within one minute.
Cleared half the missions.
Got Rank S in acts seven times.
Performed all of Sonic's actions in Act 2.
Reached the goal without dropping any of the rings you collected in GREEN HILL Act 1.
Joined the rankings.
Participated in a 30 Second Trial.
Defeated 100 enemies.
Got Rank S in acts three times.
Executed a trick with a seven-step combo or longer.
Got Rank S in an act.
Completed the first stage.