Here is the full list of all 8 Shmadow achievements.
Defeat all the bosses
Die a total of 100 times
Achieve 400,000 points
Kill over 9000 enemies
Get 100,000 points in under 100 seconds
Achieve 100,000 points on Nightmare
Defeat the same boss twice
Be fully charged and have a power up and don't use either to defeat a boss