Here is the full list of all 29 SAMURAI SHODOWN NEOGEO COLLECTION achievements.
Defeat Kuroko in Samurai Shodown II
Defeat the optional boss Mizuki in Samurai Shodown V Special or Perfect as Amakusa, Zankuro, Gaoh, or Mizuki.
Defeat the optional boss Mizuki in Samurai Shodown V Special or Perfect
Defeat the last boss Gaoh in Samurai Shodown V as Rera, Enja, Suija, or Rasetsumaru
Clear Samurai Shodown V as Poppy
Defeat the last boss Gaoh in Samurai Shodown V as Yoshitora, Yunfei, Mina, or Kusaregedo
Clear any game at its highest difficulty setting
Defeat the last boss Gaoh in Samurai Shodown V
Defeat the last boss Zankuro in Samurai Shodown III as Shizumaru, Rimururu, Gaira, or Basara
Defeat the last boss Zankuro in Samurai Shodown III as Shizumaru
Defeat the last boss Mizuki in Samurai Shodown II as Nakoruru
Perform an 'Overkill' move in Samurai Shodown V Special or Perfect
Perform a ‘Barehanded Sword Grab’ in any game
Perform a 'Honorable Death' move in Samurai Shodown IV, Samurai Shodown V, Samurai Shodown V Special, or Perfect
Perform a 'Fatal Flash' move in Samurai Shodown IV, Samurai Shodown V, Samurai Shodown V Special, or Perfect
Perform a 'Link Slash' move in Samurai Shodown IV
Perform a 'No Contest' in Samurai Shodown IV
Get a Character Specific Ending in Samurai Shodown IV
Get a Character Specific Ending in Samurai Shodown IV as Kazuki or Sogetsu
Defeat the last boss Mizuki in Samurai Shodown II as Genjuro, Cham Cham, Neinhalt, or Nicotine
Defeat the last boss Zankuro in Samurai Shodown III
Defeat the last boss Mizuki in Samurai Shodown II
Perform a 'Weapon Breaking Technique' or 'Weapon Flipping Technique'
Perform a ‘Toy Transformation’ move in Samurai Shodown II
Defeat the last boss Amakusa in Samurai Shodown as Haohmaru
Defeat the last boss Amakusa in Samurai Shodown
Win a ‘Sword Clash’ in any game
Eviscerate your opponent at the end of a match in one of the first three games
Pick up an Item delivered by the Edo Express Delivery Man in Samurai Shodown or Samurai Shodown II