Here is the full list of all 21 Rooms: The Unsolvable Puzzle achievements.
Escape the toymaker's mansion.
Earn 432 puzzle pieces.
Clear all underground levels in Mansion 4.
Clear all underground levels in Mansion 3.
Clear all underground levels in Mansion 2.
Destroy as many puppets as you can.
Earn 324 puzzle pieces.
Clear all underground levels in Mansion 1.
Make the toymaker's dream come true.
Clear all levels in Mansion 4.
Rotate rooms often.
Earn 216 puzzle pieces.
Clear all levels in Mansion3.
Don't worry about failing.
Clear all levels in Mansion 2.
Earn 130 puzzle pieces.
Move rooms often.
Earn 80 puzzle pieces.
Clear all levels in Mansion 1.
Use the lamp often.
Earn 30 puzzle pieces.